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Fertilisers and Making Ammonium Salts

Application of Ammonia

  • Global market size is estimated to be worth over £150 million with roughly 200 million tonnes produced yearly
  • Ammonia is produced in the Haber process and an important feedstock to produce:
    • Explosives
    • Polymers
    • Dyes
    • Cleaning products
    • Fertilisers

Fertilisers

  • Improve growth of crop plants
  • Can be natural (manure) or artifical with syntheic mixtures of soluble chemicals added to the soil
  • Fertilisers containing nitrogen, phosphorus and potassium are very common as these elements promote plant growth
  • Known as NPK fertilisers

  • Fertilisers replace minerals used up by plants and help prevent deficiency diseases
  • Farmers use fertilisers to not only increase crop yields but keep yields at consistent level each year

NPK

3 elements needed by plants to promote growth

  • Nitrogen
  • Phosphorus
  • Potassium

What are NPK fertilisers

  • Fertilisers containing:
    • Nitrogen
    • Phosphorus
    • Potassium

Why must the compounds found in fertilisers be soluble in water

  • Can dissolve into soil and be absorbed by the root hair cells

What ions are sources for nitrogen

  • Ammonium (NH4) and nitrates (NO3)

What ions are sources for phosphorus

  • Phosphate (PO4)

What ions are sources for potassium

  • Simple potassium ions (K+)

Examples of fertilisers

  • Ammonia nitrate
  • Ammonia sulfate
  • Ammonia phosphate
  • Potassium Nitrate
  • Urea

Problems

  • Eutrophication occurs when excessive fertilisers run off into water, leading to nutrient overload
    • Promotes algal blooms that deplete oxygenin water, harming aquatic life and disrupting ecosystems
  • Preventing this involves managing fertiliser application and implementing buffer zones near water bodies to reduce runoff

Buffer zone

  • Vegetated area near water bodies that help absorb nutrients, filter pollutants and reduce runoff
    • Thus protecting the water quality

Applications of ammonium salts

  • Plays a role in water purification by removing unwanted ions and contaminants
  • Handling and storage of ammonium salts must be done with care to prevent hazards such as explosions, particularly with ammonium nitrate

Production of ammonium salts

  • Chemists first devise ways to make chemicals synthetically in a lab before mass production
  • Ammonium salts can be produced in lab:
    • React an acid with ammonia (titration)
    • Evaporating solution and collecting crystals of ammonium salts
    • Known as batch process

  • After a synthesis route has been devised in the lab, this is then scaled up and optimised to be used with industrial processing
  • Typically increases efficiency of the process
  • In industy:
    • Ammonia and sulphuric acid will be made on site
  • Production of ammonium salts is a continuous process