Fertilisers and Making Ammonium Salts
Application of Ammonia
- Global market size is estimated to be worth over £150 million with roughly 200 million tonnes produced yearly
- Ammonia is produced in the Haber process and an important feedstock to produce:
- Explosives
- Polymers
- Dyes
- Cleaning products
- Fertilisers
Fertilisers
- Improve growth of crop plants
- Can be natural (manure) or artifical with syntheic mixtures of soluble chemicals added to the soil
- Fertilisers containing nitrogen, phosphorus and potassium are very common as these elements promote plant growth
- Known as NPK fertilisers
- Fertilisers replace minerals used up by plants and help prevent deficiency diseases
- Farmers use fertilisers to not only increase crop yields but keep yields at consistent level each year
NPK
- Nitrogen
- Phosphorus
- Potassium
What are NPK fertilisers
- Fertilisers containing:
- Nitrogen
- Phosphorus
- Potassium
Why must the compounds found in fertilisers be soluble in water
- Can dissolve into soil and be absorbed by the root hair cells
What ions are sources for nitrogen
- Ammonium (NH4) and nitrates (NO3)
What ions are sources for phosphorus
What ions are sources for potassium
- Simple potassium ions (K+)
Examples of fertilisers
- Ammonia nitrate
- Ammonia sulfate
- Ammonia phosphate
- Potassium Nitrate
- Urea
Problems
- Eutrophication occurs when excessive fertilisers run off into water, leading to nutrient overload
- Promotes algal blooms that deplete oxygenin water, harming aquatic life and disrupting ecosystems
- Preventing this involves managing fertiliser application and implementing buffer zones near water bodies to reduce runoff
Buffer zone
- Vegetated area near water bodies that help absorb nutrients, filter pollutants and reduce runoff
- Thus protecting the water quality
Applications of ammonium salts
- Plays a role in water purification by removing unwanted ions and contaminants
- Handling and storage of ammonium salts must be done with care to prevent hazards such as explosions, particularly with ammonium nitrate
Production of ammonium salts
- Chemists first devise ways to make chemicals synthetically in a lab before mass production
- Ammonium salts can be produced in lab:
- React an acid with ammonia (titration)
- Evaporating solution and collecting crystals of ammonium salts
- Known as batch process
- After a synthesis route has been devised in the lab, this is then scaled up and optimised to be used with industrial processing
- Typically increases efficiency of the process
- In industy:
- Ammonia and sulphuric acid will be made on site
- Production of ammonium salts is a continuous process